Influence of inorganic fillers on the compaction behaviour of porous polymer based membranes

被引：144

作者：

Ebert, K ^{[1
]}

Fritsch, D ^{[1
]}

Koll, J ^{[1
]}

Tjahjawiguna, C ^{[1
]}

机构：

[1] GKSS Forschungszentrum Geesthacht GmbH, Inst Chem, D-21502 Geesthacht, Germany

来源：

JOURNAL OF MEMBRANE SCIENCE | 2004年 / 233卷 / 1-2期

关键词：

membranes; PVDF; polyamideimide; titanium dioxide; compaction;

D O I：

10.1016/j.memsci.2003.12.012

中图分类号：

TQ [化学工业];

学科分类号：

0817 [化学工程与技术];

摘要：

The influence of TiO2 as inorganic filler in poly(vinylidene fluoride) (PVDF) and polyamideimide (PAT) membranes on various permeation processes has been investigated. PAI/TiO2 Membranes could be prepared without any post-treatment. Furthermore, PAT membranes with 40wt.%, TiO2 could withstand a temperature treatment at 180degreesC with only minor decrease in fluxes. The pore size distribution of the thus treated membranes remained practically unchanged. PVDF/TiO2 membranes were clearly less susceptible to compaction than pure PVDF membranes during pressure treatment at 30 bar. Additionally, hydrophilic composite membranes with either PVDF or PVDF/TiO2 supports were tested in vapour permeation experiments for the dehydration of ethanol. The tests covering a temperature range from 78 degreesC (1 bar) to 135 degreesC (6.5 bar) revealed that the membranes with the organic-inorganic support showed significantly better permeate quality even at 135 degreesC accompanied by higher fluxes within the investigated temperature range. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：71 / 78

页数：8

共 16 条

[1]

The influence of filler concentration on the compaction and filtration properties of Zirfon®-composite ultrafiltration membranes [J].

Aerts, P ;

Greenberg, AR ;

Leysen, R ;

Krantz, WB ;

Reinsch, VE ;

Jacobs, PA .

SEPARATION AND PURIFICATION TECHNOLOGY, 2001, 22-3 (1-3) :663-669

[2]

*AT CHEM INC, TECHN DAT SHEET

[3]

Beerlage M., 1994, THESIS U TWENTE

[4]

*BP AM POL INC, TECHN DAT SHEET

[5]

A comparison between polysulfone, zirconia and organo-mineral membranes for use in ultrafiltration [J].

Doyen, W ;

Adriansens, W ;

Molenberghs, B ;

Leysen, R .

JOURNAL OF MEMBRANE SCIENCE, 1996, 113 (02) :247-258

[6]

EBERT K, 2000, 19925475A1 DEOS

[7]

JONSSON G, 1978, DESALINATION, V24, P19

[8]

Kafchinski E.R., 1993, [No title captured], Patent No. [AP 5,213,689, 5213689]

[9]

Kesting R.E., 1985, SYNTHETIC POLYM MEMB, V2nd

[10]

MACDONALD W, 1974, Patent No. 3842515

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