Fabrication of MoS2 nanosheet@TiO2 nanotube hybrid nanostructures for lithium storage

被引:163
作者
Xu, Xin [1 ,2 ]
Fan, Zhaoyang [1 ,2 ]
Ding, Shujiang [1 ,2 ]
Yu, Demei [1 ,2 ]
Du, Yaping [3 ]
机构
[1] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Sch Sci, Dept Appl Chem, Xian 710049, Peoples R China
[2] Xi An Jiao Tong Univ, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Sch Sci, Dept Appl Chem, Xian 710049, Peoples R China
[3] Xi An Jiao Tong Univ, Frontier Inst Chem, Frontier Inst Sci & Technol, Coll Sci, Xian 710054, Peoples R China
基金
中国国家自然科学基金;
关键词
ION BATTERY APPLICATIONS; ANODE MATERIAL; ELECTROCHEMICAL PERFORMANCE; ASSISTED SYNTHESIS; HIERARCHICAL MOS2; TIO2; SNO2; GRAPHENE; SHELL; NANOCOMPOSITE;
D O I
10.1039/c3nr06736j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
MoS2 nanosheet@TiO2 nanotube hybrid nanostructures were successfully prepared by a facile two-step method: prefabrication of porous TiO2 nanotubes based on a sol-gel method template against polymeric nanotubes, and then assembly of MoS2 nanoclusters that consist of ultrathin nanosheets through a solvothermal process. These hybrid nanostructures were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray (EDX) spectroscopy, X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) analysis. When evaluated as an electrode material for lithium ion batteries, the results of the electrochemical test show that the unique MoS2 nanosheet@TiO2 nanotube hybrid nanostructures exhibit outstanding lithium storage performances with high specific capacity and excellent rate capability. The smart architecture of the MoS2 nanosheet@TiO2 nanotube hybrid nanostructures makes a prominent contribution to the excellent electrochemical performance.
引用
收藏
页码:5245 / 5250
页数:6
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