Elemental fluorine .3. The preparation of dialkyl fluoromalonates by direct fluorination

被引：18

作者：

Chambers, RD ^{[1
]}

Hutchinson, J ^{[1
]}

Thomson, J ^{[1
]}

机构：

[1] BNFL FLUOROCHEM LTD, PRESTON PR4 0XJ, LANCS, ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 78卷 / 02期

关键词：

elemental fluorine; preparation; dialkyl fluoromalonates; direct fluorination; NMR spectroscopy; mass spectrometry;

D O I：

10.1016/0022-1139(96)03422-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dialkyl fluoromalonates have been prepared by treating the sodium derivatives

引用

页码：165 / 166

页数：2

共 23 条

[1] FLUORONITROALIPHATICS .3. PREPARATION OF SOME NEGATIVELY SUBSTITUTED HALONITROMETHANES [J].

ADOLPH, HG ;

OESTERLI.RE ;

SITZMANN, ME .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (11) :4296-&

[2] EFFICIENT ELECTROPHILIC FLUORINATION OF BETA-DICARBONYL COMPOUNDS WITH THE SELECTFLUOR REAGENT F-TEDA-BF4 (1-CHLOROMETHYL-4-FLUORO-1,4-DIAZONIABICYCLO[2.2.2]OCTANE BIS(TETRAFLUOROBORATE)) [J].

BANKS, RE ;

LAWRENCE, NJ ;

POPPLEWELL, AL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (03) :343-344

[3] ORGANIC FLUORINE COMPOUNDS .12. PREPARATION AND REACTIONS OF DIETHYL FLUOROMALONATE [J].

BERGMANN, ED ;

COHEN, S ;

SHAHAK, I .

JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV) :3286-3289

[4]

BOEHM S, 1994, Patent No. 4237882

[5] Elemental fluorine .2. Direct fluorination of 1,3-dicarbonyl compounds [J].

Chambers, RD ;

Greenhall, MP ;

Hutchinson, J .

TETRAHEDRON, 1996, 52 (01) :1-8

[6] NUCLEOPHILIC-SUBSTITUTION VERSUS ELECTRON-TRANSFER .2. SN2 AT FLUORINE AND ELECTRON-TRANSFER ARE COMPETING AND DIFFERENT PATHWAYS IN ELECTROPHILIC FLUORINATIONS [J].

DIFFERDING, E ;

WEHRLI, M .

TETRAHEDRON LETTERS, 1991, 32 (31) :3819-3822

[7]

DIFFERDING E, 1991, SYNLETT, P187

[8] ORGANIC FLUORINE COMPOUNDS .I. REINVESTIGATION OF ACTION OF PERCHLORYL FLUORIDE ON DIETHYL MALONATE [J].

GERSHON, H ;

RENWICK, JAA ;

WYNN, WK ;

DASCOLI, R .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (03) :916-&

[9] FLUORO-OLEFINS .5. FLUORO-DIENES AND FLUORO-TRIENES AND PERFLUOROMALONIC ACID [J].

HASZELDINE, RN .

JOURNAL OF THE CHEMICAL SOCIETY, 1955, :4302-4305

[10] DIFLUOROMALONIC DERIVATIVES FROM DIFLUOROPENTANE [J].

HENNE, AL ;

DEWITT, EG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (04) :1548-1550

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