Electrochemical characteristics of LiNiO2 films prepared for charge storable electrode application

被引:13
作者
Han, Chi-Hwan [2 ]
Kim, Ji-Hoon [1 ]
Paeng, Sung-Hwan [1 ]
Kwak, Dong-Joo [1 ]
Sung, Youl-Moon [1 ]
机构
[1] Kyungsung Univ, Dept Elect Elect Engn, Pusan 608736, South Korea
[2] Korea Inst Energy Res, Sensors & Mat Res Ctr, Taejon 305343, South Korea
关键词
LiNO2; films; Molten salt synthesis; Lithium ion battery; Charge storable electrode; SUBSTITUTION;
D O I
10.1016/j.tsf.2009.02.046
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, electrochemical investigation of LiNiO2 films prepared by molten salt synthesis (MSS) method was performed to develop a storage electrode of solar cell energy. The preferred orientation constantly indicates (111), (012), (110) and (113). The microstructures confirmed the size of the LiNiO2 particles in a narrow range of similar to 200 nm. Cyclic voltammogram (CV) profiles have broad cathodic peak at 3.7 V and three anodic peaks at 3.4, 3.1 and 1.9 V. For the charge and discharge range of 2.5-4.4 V, the discharge capacity was 159 mAh/g at first, and slowly decreased to 148 mAh/g during the 30th cycles. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:4215 / 4217
页数:3
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