Cyclopropanation reactions catalysed by copper(II)-exchanged clays and zeolites. Influence of the catalyst on the selectivity

被引：27

作者：

Fraile, JM ^{[1
]}

Garcia, JI ^{[1
]}

Mayoral, JA ^{[1
]}

机构：

[1] UNIV ZARAGOZA,CSIC,FAC CIENCIAS,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN,E-50009 ZARAGOZA,SPAIN

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001319

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of ethyl diazoacetate with styrene is catalysed by Cu-II-exchanged clays and zeolites; the trans/cis Selectivity strongly depends on the nature of the catalyst and when using Cu-II-K10 montmorillonite the normal selectivity in solution is reversed and the cis-cyclopropane is the major product. The tendency of this catalyst to increase the amount of the product less favoured in solution is confirmed in other reactions.

引用

页码：1319 / 1320

页数：2

共 19 条

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