Selective and efficient platinum(0)-carbene complexes as hydrosilylation catalysts

被引：356

作者：

Markó, IE

Stérin, S

Buisine, O

Mignani, G

Branlard, P

Tinant, B

Declercq, JP

机构：

[1] Catholic Univ Louvain, Dept Chim, Unite Chim Organ & Med, B-1348 Louvain, Belgium

[2] Catholic Univ Louvain, Dept Chim, Unite Anal Struct, B-1348 Louvain, Belgium

[3] Rhodia Silicones, F-69192 St Fons, France

来源：

SCIENCE | 2002年 / 298卷 / 5591期

关键词：

D O I：

10.1126/science.1073338

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

The hydrosilylation reaction enables the production of silicon polymers. Platinum-carbene complexes are reported that catalyze the hydrosilylation reaction of alkenes with remarkable efficiency and exquisite selectivity and avoid the formation of platinum colloids. By-products, typically encountered with previous catalytic systems, are suppressed with these platinum derivatives.

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页码：204 / 206

页数：4

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