Organolanthanide catalyzed hydrogenation and hydrosilylation of substituted methylenecycloalkanes

被引：42

作者：

Molander, GA

Winterfeld, J

机构：

[1] Dept. of Chemistry and Biochemistry, University of Colorado, Boulder

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 524卷 / 1-2期

关键词：

samarium; ytterbium; silicon; lanthanides; hydrogenation; hydrosilylation;

D O I：

10.1016/S0022-328X(96)06276-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This communication presents a study of the scope of the catalytic hydrogenation and hydrosilylation of chiral exomethylene-substituted cyclopentanes and cyclohexanes utilizing the organolanthanide precatalysts Cp(2)*LnCH(SiMe(3))(2)(Cp* = C(5)Me(5); Ln = Sm, Yb). Both reaction types are sterically driven and lead to the cis-diastereomer as the major product. Additionally, the hydrosilylation is regiospecific, the silane being placed exclusively at the terminal position of the double bond.

引用

页码：275 / 279

页数：5

共 42 条

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