Effect of carbenoid structure on the reactions of rhodium-stabilized carbenoids with cycloheptatriene

被引：31

作者：

Davies, HML ^{[1
]}

Stafford, DG ^{[1
]}

Hansen, T ^{[1
]}

Churchill, MR ^{[1
]}

Keil, KM ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 13期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)00104-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium prolinate catalyzed reactions of diazocarbonyls with cycloheptatriene are very dependent on the carbenoid structure and can result in either cyclopropanation, C-H insertion or a combined C-H insertion Cope rearrangement. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：2035 / 2038

页数：4

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