Nature of asymmetry in fluid criticality

被引:75
作者
Anisimov, Mikhail A. [1 ]
Wang, Jingtao
机构
[1] Univ Maryland, Dept Chem & Biomol Engn, College Pk, MD 20742 USA
[2] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
关键词
D O I
10.1103/PhysRevLett.97.025703
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
By combining accurate liquid-vapor coexistence and heat-capacity data, we have unambiguously separated two nonanalytical contributions of liquid-gas asymmetry in fluid criticality and showed the validity of "complete scaling" [Fisher , Phys. Rev. Lett. 85, 696 (2000); Phys. Rev. E 67, 061506 (2003)]. We have also developed a method to obtain two scaling-field coefficients, responsible for the two sources of the asymmetry, from mean-field equations of state. Since the asymmetry effects are completely determined by Ising critical exponents, there is no practical need for a special renormalization-group theoretical treatment of asymmetric fluid criticality.
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页数:4
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