Dehydrohalogenation of iodoarenes to give ruthenium clusters containing mu(4)-naphthyne and mu(4)-phenanthryne ligands

被引：16

作者：

Deeming, AJ

Speel, DM

机构：

[1] Department of Chemistry, University College London, London WC1H 0AJ

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 03期

关键词：

D O I：

10.1021/om960878s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Iodobenzene and 4-iodotoluene react with [Ru-3(CO)(12)] to give the oxidative addition products [Ru-3(mu-I)(mu,eta(6)-C(6)H(4)R)(CO)(8)] (R = H, 4-Me), whereas 1-iodonaphthalene and 9-iodophenanthrene give the aryne clusters [Ru-4(mu(4),eta(2)-L)(CO)(12)] (L = 1,2-naphthyne, 9,10-phenanthryne).

引用

收藏

页码：289 / 291

页数：3

相关论文

共 16 条

[1] CARBON-CARBON BOND-CLEAVAGE BY OSMIUM CLUSTERS - RING-OPENING OF A CYCLOBUTENYL LIGAND BY A TRIOSMIUM CLUSTERS [J].

ADAMS, RD ;

QU, XS .

ORGANOMETALLICS, 1995, 14 (09) :4167-4172

[2] COORDINATION AND TRANSFORMATIONS OF BENZOTHIENYL LIGANDS BY TRIOSMIUM CLUSTER COMPLEXES [J].

ADAMS, RD ;

QU, XS .

ORGANOMETALLICS, 1995, 14 (05) :2238-2245

[3] CLEAVAGE OF ARYL CARBON-SULFUR BONDS BY A TRINUCLEAR CLUSTER - THE REACTION OF ALKYL PHENYL SULFIDES WITH OS3(CO)12 [J].

ADAMS, RD ;

KATAHIRA, DA ;

YANG, LW .

ORGANOMETALLICS, 1982, 1 (02) :235-239

[4] TRIPLE OXIDATIVE ADDITION OF THE DISELENIDE PHSESEPH TO THE CLUSTER [OS3(CO)10(MECN)2] TO GIVE THE OSMIUM(II) COMPOUND [OS3(MU-PH)(MU-PHCO)(MU-3-SE)2(CO)8] [J].

ARCE, AJ ;

ARROJO, P ;

DEEMING, AJ ;

DESANCTIS, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (20) :1491-1492

[5] ETA(1)-ARYL-BRIDGED TRIRUTHENIUM CLUSTER COMPLEXES [J].

CABEZA, JA ;

FRANCO, RJ ;

LLAMAZARES, A ;

RIERA, V ;

PEREZCARRENO, E ;

VANDERMAELEN, JF .

ORGANOMETALLICS, 1994, 13 (01) :55-59

[6] THE REACTION OF PHSR(R=FC OR PH) WITH RU-3(CO)(12) [J].

CULLEN, WR ;

RETTIG, SJ ;

ZHENG, TC .

POLYHEDRON, 1995, 14 (19) :2653-2661

[7] NAPHTHYNE - OSMIUM AND RUTHENIUM CLUSTER DERIVATIVES [J].

CULLEN, WR ;

RETTIG, SJ ;

ZHENG, TC .

ORGANOMETALLICS, 1995, 14 (03) :1466-1470

[8]

DEEMING AJ, 1986, ADV ORGANOMET CHEM, V26, P1

[9] TRIOSMIUM CLUSTERS WITH 2-PYRIDYLPHOSPHINES AS LIGANDS [J].

DEEMING, AJ ;

SMITH, MB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (22) :3383-3391

[10]

DEEMING AJ, 1996, J CHEM SOC CHEM COMM, P53