A solid-polymer electrolyte direct methanol fuel cell with a mixed reactant and air anode

被引:40
作者
Shukla, AK [1 ]
Jackson, CL [1 ]
Scott, K [1 ]
Murgia, G [1 ]
机构
[1] Newcastle Univ, Dept Chem & Proc Engn, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
基金
英国工程与自然科学研究理事会;
关键词
mixed-reactant anode; selective anode; direct methanol fuel cell; numerical modelling;
D O I
10.1016/S0378-7753(02)00232-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A comparison of the performance of a solid-polymer electrolyte direct methanol fuel cell (SPE-DMFC) with aqueous methanol and air mixed at the anode, and with only aqueous methanol is presented. The performance of the mixed methanol reactant and air fed anode SPE-DMFC is superior to the conventional methanol only fed anode SPE-DMFC. The experimental performance of the mixed-reactant anode SPE-DMFC are compared with results of a numerical modelling based on phenomenological transport equations for electrocatalyst layer, diffusion layer and the polymer electrolyte membrane. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:43 / 51
页数:9
相关论文
共 29 条
[1]   Recent advances in fuel cell technology and its applications [J].
Acres, GJK .
JOURNAL OF POWER SOURCES, 2001, 100 (1-2) :60-66
[2]  
[Anonymous], 1964, ELECTROCHIM ACTA
[3]  
Aricò AS, 2001, FUEL CELLS, V1, P133
[4]   Performance of a one-chamber solid oxide fuel cell with a surface-modified zirconia electrolyte [J].
Asano, K ;
Iwahara, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (09) :3125-3130
[5]   Mixed-reactant, strip-cell direct methanol fuel cells [J].
Barton, SC ;
Patterson, T ;
Wang, E ;
Fuller, TF ;
West, AC .
JOURNAL OF POWER SOURCES, 2001, 96 (02) :329-336
[6]  
BEAR J, 1960, DYNAMICS FLUIDS PORO
[7]   A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].
BERNARDI, DM ;
VERBRUGGE, MW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (09) :2477-2491
[8]   MATHEMATICAL-MODEL OF A GAS-DIFFUSION ELECTRODE BONDED TO A POLYMER ELECTROLYTE [J].
BERNARDI, DM ;
VERBRUGGE, MW .
AICHE JOURNAL, 1991, 37 (08) :1151-1163
[9]  
DELARUE RE, 1959, J ELECTROCHEM SOC, V106, P827
[10]   A NOVEL THIN-FILM ELECTROCHEMICAL DEVICE FOR ENERGY-CONVERSION [J].
DYER, CK .
NATURE, 1990, 343 (6258) :547-548