3-cyanomethyl-2-vinylindoles as thermal indole-2,3-quinodimethane equivalents: synthesis of functionalized 1,2,3,4-tetrahydrocarbazoles

被引：31

作者：

Laronze, M ^{[1
]}

Sapi, J ^{[1
]}

机构：

[1] Univ Reims, Fac Pharm, CNRS, UMR 6013, F-51096 Reims, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 44期

关键词：

Diels-Alder reaction; 3-cyanomethyl-2-vinylindole; indole-2,3-quinodimethane; 1,5]-sigmatropic hydrogen shift; tetrahydrocarbazoles;

D O I：

10.1016/S0040-4039(02)01907-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electron-donating substituted 3-cyanomethyl-2-vinylindoles were found to rearrange via thermal [1,5]H shift into the corresponding indole-2,3-quinodimethanes which were trapped by dienophiles to afford tetrahydrocarbazoles. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：7925 / 7928

页数：4

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