Ruthenium-catalysed cross metathesis binding of functionalized olefins to polystyrene resin via a novel allylsilyl linker suitable for electrophilic cleavage

被引:66
作者
Schuster, M [1 ]
Lucas, N [1 ]
Blechert, S [1 ]
机构
[1] TECH UNIV BERLIN,INST ORGAN CHEM,SEKR C3,D-10623 BERLIN,GERMANY
关键词
D O I
10.1039/a701122i
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1% Divinylbenzene-crosslinked allyldimethylsilyl polystyrene 1 undergoes highly efficient ruthenium-catalysed cross-metathesis with functionalized terminal olefins and allows electrophilic cleavage of the resulting functionalized allylsilane.
引用
收藏
页码:823 / 824
页数:2
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