Cross-coupling reactions on azoles with two and more heteroatoms

被引：306

作者：

Schnurch, Michael ^{[1
]}

Flasik, Radoslav ^{[1
]}

Khan, Ather Farooq ^{[1
]}

Spina, Markus ^{[1
]}

Mihovilovic, Marko D. ^{[1
]}

Stanetty, Peter ^{[1
]}

机构：

[1] Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 2006卷 / 15期

关键词：

heterocycles; nitrogen heterocycles; oxygen heterocycles; sulfur heterocycles; C-H activation;

D O I：

10.1002/ejoc.200600089

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent progress in the field of transition-metal-catalyzed cross-coupling reactions on various azole systems is summarized. Most important C-C- and C-X-bond formation methodologies (Negishi, Suzuki-Miyaura, Stille, Kumada-Corriu-Tamao, Hiyama, Sonogashira, Heck, C-H activation) are reviewed and discussed for the imidazole, oxazole, thiazole, pyrazole, isoxazole, and isothiazole system, as well as for azoles with more than two heteroatoms. This review covers the literature that appeared in the past ten years up to the end of 2005 with corresponding azoles used either as metal organyl or halide (including triflates and some other less frequently applied leaving groups); literature describing azole structures only as ligands was not included. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

引用

页码：3283 / 3307

页数：25

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