Thermal stability study of some azo-derivatives and their complexes - Part 2. New azo-derivative pigments and their Cu(II) complexes

被引:36
作者
Badea, M
Olar, R
Cristurean, E
Marinescu, D
Emandi, A
Budrugeac, P
Segal, E
机构
[1] Univ Bucharest, Dept Inorgan Chem, Bucharest 71267, Romania
[2] Res & Dev Inst Elect Engn, ICPE CA, Bucharest 74204, Romania
[3] Univ Bucharest, Dept Phys Chem, Bucharest, Romania
关键词
azo-derivatives; Cu(II) complex; non-isothermal kinetics; thermal stability;
D O I
10.1023/B:JTAN.0000041660.12310.c7
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper deals with the investigation concerning the thermal stability of two new azo-derivatives and their Cu(II) complexes of type [Cu(L(1))(2)] and, respectively, ((C(4)H(9))(4)N)(2)[Cu(L(2))(2)]. The thermal decomposition steps have been put in evidence. For the kinetically workable ones, the values of the activation energy vs. conversion degree were determined.
引用
收藏
页码:815 / 824
页数:10
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