Furan-fused 3-sulfolene as a novel building block: Intermolecular Diels-Alder reactions of 4H,6H-thieno[3,4-c]furan 5,5-dioxide

被引：10

作者：

Suzuki, T ^{[1
]}

Kubomura, K ^{[1
]}

Takayama, H ^{[1
]}

机构：

[1] TEIKYO UNIV,FAC PHARMACEUT SCI,SAGAMIKO,KANAGAWA 19901,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 03期

关键词：

D O I：

10.1039/a604600b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A furan-fused 3-sulfolene 4N,6H-thieno[3,4-c]furan 5,5-dioxide 1, can be used as a bis-diene, reacting sequentially with a variety of dienophiles to construct four types of skeleton, depending on the dienophile and the reaction conditions. The 3-sulfolene moiety of the furansulfolene not only functions as the s-cis-diene part in Diels-Alder reactions, but also extends the range of the Diels-Alder reactions of the furan moiety with various dienophiles through its desulfonylation to form the s-cis-diene.

引用

页码：251 / 256

页数：6

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