Synthesis and transition metal coordination of 2-(azidomethyl) phenyl isocyanide

被引：11

作者：

Facchin, G

Michelin, RA

Mozzon, M

Pugliese, S

Sgarbossa, P

Tassan, A

机构：

[1] Univ Padua, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

[2] CNR, Dipartimento Proc Chim Ingn, ISTM, I-35131 Padua, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 11期

关键词：

isocyanide; functionalized isocyanide; azido; transition metal complexes;

D O I：

10.1016/S1387-7003(02)00598-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-(chloromethyl)phenyl formamide, 2-(CH2Cl)C6H4NHCHO, with NaN3 in DMSO at room temperature affords 2-(azidomethyl)phenyl formamide, 2-(CH2N3)C6H4NHCHO (1), which is then dehydrated to 2-(azidomethyl)phenyl isocyanide, 2-(CH2N3)C(6)H(4)Nequivalent toC, (2) upon reaction with SOCl2 in DMF at low temperature. The coordination ability of the isocyanide 2 has been tested towards some Pt(II), Pd(II) and W(0) metal complexes to yield derivatives of the type [PtCl2(CNC6H4-2-CH2N3)(2)], [PdCl2(CNC6H4-2-CH2N3)(PPh3)] and [W(CO)(5)(CNC6H4-2-CH2N3)], respectively. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：915 / 918

页数：4

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