alpha,omega-alkanediyldiindium

被引：28

作者：

Tschinkl, M ^{[1
]}

Schier, A ^{[1
]}

Riede, J ^{[1
]}

Schmidt, E ^{[1
]}

Gabbai, FP ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,D-85747 GARCHING,GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 22期

关键词：

D O I：

10.1021/om970498m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of indium(I) bromide with alpha,omega-alkanediylbis(bromomercury) complexes (alkane = butane, pentane, and hexane) resulted in formation of the corresponding alpha,omega-alkanediylbis(dibromoindium) compounds, which were isolated as THF adducts. The THF molecules of the complexes are easily displaced Ey bromide anions, thus affording the corresponding alpha,omega-alkanediylbis(tribromoindate) dianions.

引用

页码：4759 / 4761

页数：3

共 18 条

[1] DESIGN OF ANION RECEPTORS - APPLICATIONS [J].

DIETRICH, B .

PURE AND APPLIED CHEMISTRY, 1993, 65 (07) :1457-1464

[2] A heteronuclear trifunctional Lewis acid [J].

Gabbai, FP ;

Schier, A ;

Riede, J .

CHEMICAL COMMUNICATIONS, 1996, (10) :1121-1122

[3] Indium as an electrophilic center in polyfunctional Lewis acids [J].

Gabbai, FP ;

Schier, A ;

Riede, J ;

Schichl, D .

ORGANOMETALLICS, 1996, 15 (20) :4119-4121

[4]

HILPERT S, 1914, CHEM BER, V47, P177

[5] THE FIRST WATER-DEPENDENT LIQUID CLATHRATE - X-RAY EVIDENCE IN THE SOLID FOR A C-H...PI(HETEROARENE)...INTERACTION [J].

HUNTER, R ;

HAUEISEN, RH ;

IRVING, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (05) :566-568

[6] SYNTHESIS AND TRANSPORT-PROPERTIES OF 12-SILACROWN-3, A NEW TYPE OF ANION COMPLEXING AGENT [J].

JUNG, ME ;

XIA, HJ .

TETRAHEDRON LETTERS, 1988, 29 (03) :297-300

[7] 1,5,9-TRISTANNACYCLODODECANES AS LEWIS-ACIDS - NOVEL STRUCTURE OF A CHLORIDE COMPLEX [J].

JURKSCHAT, K ;

KUIVILA, HG ;

LIU, SC ;

ZUBIETA, JA .

ORGANOMETALLICS, 1989, 8 (12) :2755-2759

[8] THE SEARCH FOR SELECTIVE, NEUTRAL ANION RECEPTORS [J].

KAUFMANN, DE ;

OTTEN, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (18) :1832-1834

[9] PREPARATION AND CRYSTAL-STRUCTURE DETERMINATION OF THE INDIUM METHYLENE COMPLEXES CL2INCH2INCL2.2TMEN AND CL(BR)INCH2INCL2.2TMEN (TMEN = "N,N,N',N'-TETRAMETHYLETHANEDIAMINE) [J].

KHAN, MA ;

PEPPE, C ;

TUCK, DG .

ORGANOMETALLICS, 1986, 5 (03) :525-530

[10] SYNTHESIS AND MOLECULAR-STRUCTURE OF A BIS[DI(ALKYL)ALANYL]METHANE - (CH(SIME3)2)2AL-CH2-AL(CH(SIME3)2)2 [J].

LAYH, M ;

UHL, W .

POLYHEDRON, 1990, 9 (2-3) :277-282

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