Low density equation of state of asymmetric hard sphere mixtures

被引：28

作者：

Enciso, E ^{[1
]}

Almarza, NG ^{[1
]}

Calzas, DS ^{[1
]}

Gonzalez, MA ^{[1
]}

机构：

[1] INST MAX VON LAUE PAUL LANGEVIN, F-38042 GRENOBLE 9, FRANCE

来源：

MOLECULAR PHYSICS | 1997年 / 92卷 / 02期

关键词：

D O I：

10.1080/00268979709482086

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The equation of state of highly asymmetric hard sphere mixtures at low and moderate densities is investigated using NpT Monte Carlo simulations. The discrepancies of the estimated fifth Virial coefficient with the reported values of Saija et al. (Saija, F., Fiumara, G. and Giaquinta, P. V., 1996, Molec. Phys., 89, 1181) led us to compute such a coefficient. The new results are fully compatible with the compressibility factors estimated by Monte Carlo simulation and show excellent agreement with the predicted coefficients from the Boublik and Mansoori et al. equation of state.

引用

页码：173 / 176

页数：4

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