Synthesis, electrochemistry, Langmuir-Blodgett deposition and photophysics of metal-coordinated fullerene-porphyrin dyads

被引：39

作者：

Da Ros, T

Prato, M

Carano, M

Ceroni, P

Paolucci, F

Roffia, S

Valli, L

Guldi, DM

机构：

[1] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[3] Dipartimento Ingn Innovaz, Edificio La Stecca, I-73100 Lecce, Italy

[4] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46656 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 599卷 / 01期

关键词：

fullerenes; ruthenium; porphyrin; Langmuir-Blodgett; photophysics;

D O I：

10.1016/S0022-328X(99)00754-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel fullerene-Ru-porphyrin conjugate (3b) for Langmuir-Blodgett (LB) film deposition has been synthesized. The side polar chain that characterizes the complex is necessary to introduce enough amphiphilicity in these otherwise non-polar moieties. The complex can be deposited on solid substrates via the LB technique and the films obtained show charge separation upon light irradiation. In addition, a careful cyclic voltammetry study of the complex is reported. (C) 2000 Elsevier Science S.A, All rights reserved.

引用

页码：62 / 68

页数：7

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