Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation

被引：47

作者：

Hill, Jonathan P.

Wakayama, Yutaka

Schmitt, Wolfgang

Tsuruoka, Tohru

Nakanishi, Takashi

Zandler, Melvin L.

McCarty, Amy L.

D'Souza, Francis

Milgrom, Lionel R.

Ariga, Katsuhiko

机构：

[1] Int Sci Young Scientists, Tsukuba, Ibaraki 3050044, Japan

[2] Nanomat Assembly Grp, Tsukuba, Ibaraki 3050044, Japan

[3] Atom Elect Grp, Tsukuba, Ibaraki 3050044, Japan

[4] Natl Inst Mat Sci, Supermol Grp, Tsukuba, Ibaraki 3050044, Japan

[5] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

[6] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London WC2, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 22期

关键词：

D O I：

10.1039/b517668a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation state of the phenol-substituted porphyrin TDtBHPP is coupled with its structure so that its 2-electron oxidation leads to a coplanarization of the molecule and a substantial stabilization of its surface self-assembled structures adsorbed at metal substrates.

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页码：2320 / 2322

页数：3

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