Atypical stoichiometry for a 3D bimetallic oxalate-based long-range ordered magnet exhibiting high proton conductivity

被引：41

作者：

Maxim, Catalin ^{[1
,2
,3
]}

Ferlay, Sylvie ^{[1
,6
]}

Tokoro, Hiroko ^{[4
]}

Ohkoshi, Shin-Ichi ^{[4
]}

Train, Cyrille ^{[2
,5
,6
]}

机构：

[1] Univ Strasbourg, UMR UDS CNRS 7140, Mol Tecton Lab, Inst Le Bel, F-67000 Strasbourg, France

[2] CNRS, LNCMI, F-38042 Grenoble 9, France

[3] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 020464, Romania

[4] Univ Tokyo, Sch Sci, Dept Chem, Tokyo 1130033, Japan

[5] Univ Grenoble Alpes, LNCMI, F-38041 Grenoble 9, France

[6] Inst Univ France, F-75005 Paris, France

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 42期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; MN-II; FERROMAGNETISM; CROSSOVER; DESIGN; FIELD; CR; OX;

D O I：

10.1039/c4cc00607k

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)(5)[ (Mn2Cr3III)-Cr-II(ox)(9)]center dot 10H(2)O, with an unusual MnII/CrIII ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.

引用

页码：5629 / 5632

页数：4

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