Novel single and double diiron oxadithiolates as models for the active site of [Fe]-Only hydrogenases

被引：121

作者：

Song, LC ^{[1
]}

Yang, ZY

Bian, HZ

Hu, QM

机构：

[1] Nankai Univ, Dept Chem, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 13期

关键词：

D O I：

10.1021/om049752i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The series of diiron oxadithiolate model complexes for the active site of [Fe]-only hydrogenases Fe-2(mu-SCH2OCH2S-mu)(CO)(6) (1), [Fe-2(mu-SCH2OCH2S-mu)(CN)(2)(CO)(4)] (Et4N)(2) (2), [Fe-2(mu-SCH2OCH2S-mu)(CN)(CO)(5)](Et4N) (3), Fe-2(mu-SCH2OCH2S-mu)(CO)(5)[CpFe(CO)(2)(SPh)] (4), and [Fe-2(mu-SCH2OCH2S-mu) (CO)(5)](2) [(eta(5)-Ph2PC5H4)(2) Fe] (5) have been synthesized and fully characterized by elemental analysis, spectroscopy, and X-ray diffraction analysis. The structural features for some of the model complexes are compared with the corresponding features for the active site of [Fe]-only hydrogenases.

引用

页码：3082 / 3084

页数：3

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