A study on the exchange kinetics of ion-exchange fiber

被引:37
作者
Chen, LQ [1 ]
Yang, GL [1 ]
Zhang, J [1 ]
机构
[1] HEBEI UNIV, DEPT CHEM, BAODING 071002, HEBEI PROVINCE, PEOPLES R CHINA
关键词
ion-exchange fiber; ion-exchange kinetics; radioactive trace element; Gadolinium;
D O I
10.1016/1381-5148(95)00070-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, the ion-exchange kinetics of ion-exchange fiber has been studied, Under Finite Solution Volume (FSV), not only the effect of temperature, speed of stir, concentration and Ph value of the solution on the heterophase isotope exchange has been investigated, but the analytical solution of the exchange equation have also been obtained. By use of these solutions, the intraparticle diffusion coefficients D and the film transmitting coefficients D/delta under different conditions were calculated. Meanwhile, the reason why the ion-exchange rate of fiber is much faster than that of conventional spherical resins was also given with a proposed mechanism.
引用
收藏
页码:139 / 144
页数:6
相关论文
共 18 条
[1]  
ASAMI T, 1985, Patent No. 4514367
[2]  
CHEN LQ, 1993, CHIN J CHROMATOGR, V11, P265
[3]  
CHEN XQ, 1985, J NUCL RADIO CHEM, V5, P238
[4]  
DARRY DS, 1980, ANAL CHEM, V52, P1874
[5]   ANNULAR HELICAL SUPPRESSOR FOR ION CHROMATOGRAPHY [J].
DASGUPTA, PK .
ANALYTICAL CHEMISTRY, 1984, 56 (01) :103-105
[6]  
KUCERA E, 1965, J CHROMATOGR, V19, P237
[7]  
LIN W, 1992, CHIN J REACT POLYM, V1, P133
[8]  
SOLDATOV VS, 1994, ZH FIZ KHIM+, V68, P763
[9]   HOLLOW FIBER ION-EXCHANGE SUPPRESSOR FOR ION CHROMATOGRAPHY [J].
STEVENS, TS ;
DAVIS, JC ;
SMALL, H .
ANALYTICAL CHEMISTRY, 1981, 53 (09) :1488-1492
[10]   PACKED HOLLOW FIBER SUPPRESSORS FOR ION CHROMATOGRAPHY [J].
STEVENS, TS ;
JEWETT, GL ;
BREDEWEG, RA .
ANALYTICAL CHEMISTRY, 1982, 54 (07) :1206-1208