Solvent-regulated ordering in block copolymers

被引:167
作者
Alexandridis, P [1 ]
Spontak, RJ
机构
[1] SUNY Buffalo, Dept Chem Engn, Buffalo, NY 14260 USA
[2] Univ Freiburg, Inst Makromol Chem, D-79104 Freiburg, Germany
[3] N Carolina State Univ, Dept Chem Engn, Raleigh, NC 27695 USA
[4] N Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA
关键词
D O I
10.1016/S1359-0294(99)00022-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Studies of the structural polymorphism exhibited by block copolymers in the presence of selective solvents are relatively recent, but very promising in terms of fundamental understanding and practical applications. Highlighting recent advances, this review progresses from 'dry' ordered copolymers to solvated ordered (gel-like) copolymers and lastly to solvated disordered (but focally organized) copolymers. Organic- and aqueous-solvent-based systems are concurrently examined to cross-fertilize polymer and colloid science.
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页码:130 / 139
页数:10
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