Spectroscopy of isolated gramicidin peptides

被引:71
作者
Abo-Riziq, Ali [1 ]
Crews, Bridgit O. [1 ]
Callahan, Michael P. [1 ]
Grace, Louis [1 ]
de Vries, Mattanjah S. [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
关键词
gramicidin; IR-UV hole burning; peptide folding; spectroscopy; structure elucidation;
D O I
10.1002/anie.200601516
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) An eye for detail: Double-resonant IR-UV spectroscopy of isolated gramicidin peptides in the gas phase shows evidence for a helical structure, similar to that in the condensed phase. This approach probes local details in isolated molecules, free of interactions. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5166 / 5169
页数:4
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