Encapsulation of nanosized magnetic iron oxide by polyacrylamide via inverse miniemulsion polymerization

被引:131
作者
Xu, ZZ
Wang, CC [1 ]
Yang, WL
Deng, YH
Fu, SK
机构
[1] Fudan Univ, Dept Macromol Sci, Shanghai 200433, Peoples R China
[2] Fudan Univ, Key Lab Mol Engn Polymers Minist Educ, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
nanosized iron oxide particle; superparamagnetic; inverse miniemulsion polymerization; encapsulation; polyacrylamide magnetic particle;
D O I
10.1016/j.jmmm.2003.10.018
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyacrylamide particles containing nanosized magnetic iron oxide were prepared via inverse miniemulsion polymerization in this paper. The particle size of magnetic polymeric particles is about 100 nm, and these particles are superparamagnetic. The relative parameters of the miniemulsion polymerization, such as the surfactant content, ultrasonicating time, Fe3O4 and N, N'-methylene bis acrylamide content, were studied in detail. The iron oxide nanoparticles were characterized by X-ray diffraction and transmission electron microscopy (TEM). The final magnetic polymeric particles were characterized by TEM, scanning electron microscopy, dynamic light scattering, magnetization analysis and thermogravimetric analysis. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:136 / 143
页数:8
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