Improved process for chloroxidation of aryl sulfides to aryl sulfonyl chlorides in commercial grade formic acid

被引：14

作者：

Wang, Chen ^{[1
]}

Hamilton, Christopher ^{[1
]}

Meister, Phillip ^{[1
]}

Menning, Catherine ^{[1
]}

机构：

[1] Dow Chem Co USA, Midland, MI 48674 USA

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2007年 / 11卷 / 01期

关键词：

D O I：

10.1021/op0602223

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This paper discusses the process advantages of using commercial grade formic acid as the solvent for chlorine gas oxidation of aryl sulfides to sulfonyl chlorides. Compared to chloroxidation in methylene chloride, the chloroxidation in formic acid gave a consistently higher yield and easy product isolation for a sulfonyl chloride intermediate which was used in the production of the sulfonamide herbicide, penoxsulam.

引用

页码：52 / 55

页数：4

共 16 条

[1]

ARNDT K, 2003, Patent No. 6645918

[2] THE CLEAVAGE OF ORGANIC SULFIDES WITH CHLORINE [J].