Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts

被引:647
作者
Baleizao, Carlos
Garcia, Hermenegildo
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] Inst Super Tecn, Ctr Quim Fis Mol, P-1049001 Lisbon, Portugal
关键词
D O I
10.1021/cr050973n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This review discusses the efforts aimed at setting up methodologies for recovering and reuse of chiral sales ligands. Coverage is on the literature up to the beginning of 2006 with special emphasis on the most recent developments. Topics discussed include reusable chiral salen complexes operating as homogeneous catalysts, reusable chiral salen complexes supported on inorganic solids as heterogeneous catalysts, reusable chiral salen complexes supported on carbon as heterogeneous catalysts, reusable chiral salen complexes anchored on organic polymers as heterogeneous catalysts and reusable hybrid chiral metallosen-silica materials as heterogeneous catalysts.
引用
收藏
页码:3987 / 4043
页数:57
相关论文
共 379 条
[1]   Asymmetric catalysis of carbon-carbon bond-forming reactions using metal(salen) complexes [J].
Achard, TRJ ;
Clutterbuck, LA ;
North, M .
SYNLETT, 2005, (12) :1828-1847
[2]  
ADACHI K, 2001, CLAY SCI ENG P INT S
[3]   Recycling of the homogeneous Co-Jacobsen catalyst through solvent-resistent nanofiltration (SRNF) [J].
Aerts, S ;
Weyten, H ;
Buekenhoudt, A ;
Gevers, LEM ;
Vankelecom, IFJ ;
Jacobs, PA .
CHEMICAL COMMUNICATIONS, 2004, (06) :710-711
[4]   ACTIVATION OF CARBON-DIOXIDE WITH ALUMINUM PORPHYRIN AND REACTION WITH EPOXIDE - STUDIES ON (TETRAPHENYLPORPHINATO)ALUMINUM ALKOXIDE HAVING A LONG OXYALKYLENE CHAIN AS THE ALKOXIDE GROUP [J].
AIDA, T ;
INOUE, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (05) :1304-1309
[5]   Polymer-bound aluminium salen complex as reusable catalysts for CO2 insertion into epoxides [J].
Alvaro, M ;
Baleizao, C ;
Carbonell, E ;
El Ghoul, M ;
García, H ;
Gigante, B .
TETRAHEDRON, 2005, 61 (51) :12131-12139
[6]   CO2 fixation using recoverable chromium salen catalysts:: use of ionic liquids as cosolvent or high-surface-area silicates as supports [J].
Alvaro, M ;
Baleizao, C ;
Das, D ;
Carbonell, E ;
García, H .
JOURNAL OF CATALYSIS, 2004, 228 (01) :254-258
[7]   Sidewall functionalization of single-walled carbon nanotubes with nitrile imines. Electron transfer from the substituent to the carbon nanotube [J].
Alvaro, M ;
Atienzar, P ;
de la Cruz, P ;
Delgado, JL ;
Garcia, H ;
Langa, F .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (34) :12691-12697
[8]   Origins, current status, and future challenges of green chemistry [J].
Anastas, PT ;
Kirchhoff, MM .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :686-694
[9]  
Andrade CKZ, 2005, CURR ORG CHEM, V9, P195
[10]  
Angelino MD, 1999, J POLYM SCI POL CHEM, V37, P3888, DOI 10.1002/(SICI)1099-0518(19991101)37:21<3888::AID-POLA2>3.0.CO