Preparation of polymer-supported ligands and metal complexes for use in catalysis

被引：961

作者：

Leadbeater, NE ^{[1
]}

Marco, M ^{[1
]}

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 10期

关键词：

D O I：

10.1021/cr010361c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Preparation of polymer-supported ligands and metal complexes for use in catalysis was discussed. Grafting ligands onto prefabricated supports, the copolymerization of suitably derivatized ligand precursors with styrene and divinylbenzene (DVB) as a route to immobilized organometallics was also discussed. Results showed that it was not always possible to remove metal complexes from solution using crown ethers or other cryptands.

引用

页码：3217 / 3273

页数：57

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