In Search of a Chemiluminescence 1,4-Dioxy Biradical

被引：34

作者：

Bos, Richard ^{[1
]}

Tonkin, Sarah A. ^{[1
]}

Hanson, Graeme R. ^{[2
]}

Hindson, Christopher M. ^{[1
]}

Lim, Kieran F. ^{[1
]}

Barnett, Neil W. ^{[1
]}

机构：

[1] Deakin Univ, Sch Life & Environm Sci, Waurn Ponds, Vic 3217, Australia

[2] Univ Queensland, Ctr Magnet Resonance, Brisbane, Qld 4072, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 08期

关键词：

MAGNETIC-RESONANCE-SPECTROSCOPY; PEROXYOXALATE CHEMILUMINESCENCE; ACTIVATION PARAMETERS; EXCITATION STEP; MECHANISM; 1,2-DIOXETANEDIONE; THERMOCHEMISTRY; DECOMPOSITION; INTERMEDIATE; OXYGEN;

D O I：

10.1021/ja808401p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron paramagnetic resonance spectroscopy has afforded the identification of a much postulated 1,4-dioxy biradical that occurs within the light producing pathway of peroxyoxalate chemiluminescence.

引用

页码：2770 / +

页数：3

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