Lithio(diphenylphosphino)methane-tetramethylethylenediamime: It's a dimer!

被引：18

作者：

Blaurock, S ^{[1
]}

Kuhl, O ^{[1
]}

HeyHawkins, E ^{[1
]}

机构：

[1] UNIV LEIPZIG, INST ANORGAN CHEM, D-04103 LEIPZIG, GERMANY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 04期

关键词：

D O I：

10.1021/om9609022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure determination of the tetramethylethylenediamine (TMEDA) adduct of lithio-(diphenylphosphino)methane has shown this compound to be dimeric in the solid state rather than monomeric as reported previously.

引用

页码：807 / 808

页数：2

共 3 条

[1] SYNTHESIS OF ALPHA-PHOSPHORUS, GAMMA-PHOSPHORUS FUNCTIONALIZED ALKYL LITHIUM SPECIES - X-RAY STRUCTURES OF [(LI(L)(CH2PMER))2][L=NNN'N'-TETRAMETHYLETHYLENEDIAMINE (TMEN), R = ME OR PH, L=(-)SPARTEINE, R = PH] AND [LI(TMEN)(CH(SIME3)C6H4PPH2-O)] [J].

BYRNE, LT ;

ENGELHARDT, LM ;

JACOBSEN, GE ;

LEUNG, WP ;

PAPASERGIO, RI ;

RASTON, CL ;

SKELTON, BW ;

TWISS, P ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (01) :105-113

[2] LITHIO(DIPHENYLPHOSPHINO)METHANE TETRAMETHYLETHYLENEDIAMINE - CRYSTAL-STRUCTURE AND NMR-STUDIES OF A COORDINATIVELY UNSATURATED, MONOMERIC ORGANO-LITHIUM [J].

FRAENKEL, G ;

WINCHESTER, WR ;

WILLIARD, PG .

ORGANOMETALLICS, 1989, 8 (10) :2308-2311

[3]

SCHLEYER PV, 1984, J AM CHEM SOC, V106, P6468

← 1 →