Reaction of 2-formyl imidazole with intermediates from the Baylis-Hillman reaction

被引：24

作者：

Drewes, SE ^{[1
]}

Horn, MM ^{[1
]}

Ramesar, N ^{[1
]}

机构：

[1] Univ Natal, Dept Chem & Chem Technol, ZA-3209 Pietermaritzburg, South Africa

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 06期

关键词：

D O I：

10.1080/00397910008087122

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of formyl imidazole (in the presence and absence of DABCO, and with either THF or methanol as solvent) with alpha-hydroxylaryl derivatives of methyl acrylate affords novel synthetic intermediates. By controlling the reaction conditions, either allylic substitution products (THF, DABCO) or rearrangement (MeOH, no DABCO) products result.

引用

页码：1045 / 1055

页数：11

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