Zeolite-based photocatalysts

被引：249

作者：

Corma, A ^{[1
]}

Garcia, H ^{[1
]}

机构：

[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 13期

关键词：

D O I：

10.1039/b400147h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compartmentalised intracrystalline void space of zeolites are specially suited to incorporate and organise photoactive guests that can be used as photocatalysts. The rigid micropores allow assembly of multicomponent systems comprising of antenna and relays reminiscent of natural photosynthetic centers. Besides inorganic metal oxide clusters, zeolites as host are particularly attractive to construct organic photocatalysts since the guest becomes significantly stabilized by incorporation. This review gives special emphasis to the commercial and potential application of photocatalysts.

引用

页码：1443 / 1459

页数：17

共 206 条

[1] ABOULGHEIT AK, 2001, STUD SURF SCI CATAL, V135, P5011
[2] Titanium-catalyzed heterogeneous oxidations of silanes, chiral allylic alcohols, 3-alkylcyclohexanes, and thianthrene 5-oxide:: A comparison of the reactivities and selectivities for the large-pore zeolite Ti-β, the mesoporous Ti-MCM-41, and the layered alumosilicate Ti-ITQ-2
Adam, W
Corma, A
García, H
Weichold, O
[J]. JOURNAL OF CATALYSIS, 2000, 196 (02) : 339 - 344
[3] Ship-in-a-bottle synthesis of 2,4,6-triphenylthiapyrylium cations encapsulated in zeolites Y and beta: a novel robust photocatalyst
Alvaro, M
Carbonell, E
Garcia, H
Lamaza, C
Pillai, MN
[J]. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2004, 3 (02) : 189 - 193
[4] Intrazeolite photochemistry .16. Fluorescence of methylviologen adsorbed within medium- and large-pore zeolites
Alvaro, M
Facey, GA
Garcia, H
Garcia, S
Scaiano, JC
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (46) : 18173 - 18176
[5] A "Camel through the eye of a needle":: Direct introduction of the TPP+ ion inside Y-zeolites by formal ion exchange in aqueous medium
Amat, AM
Arques, A
Bossmann, SH
Braun, AM
Göb, S
Miranda, MA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (14) : 1653 - 1655
[6] PHOTOFORMATION OF (O2-)ADS RADICALS AND THEIR REACTIVITY ON POROUS VYCOR GLASS
ANPO, M
YUN, C
KUBOKAWA, Y
[J]. JOURNAL OF CATALYSIS, 1980, 61 (01) : 267 - 269
[7] ANPO M, 1993, STUD SURF SCI CATAL, V75, P2155
[8] Design of photocatalysts encapsulated within the zeolite framework and cavities for the decomposition of NO into N2 and O2 at normal temperature
Anpo, M
Zhang, SG
Mishima, H
Matsuoka, M
Yamashita, H
[J]. CATALYSIS TODAY, 1997, 39 (03) : 159 - 168
[9] PREPARATION AND CHARACTERIZATION OF THE CU+/ZSM-5 CATALYST AND ITS REACTION WITH NO UNDER UV IRRADIATION AT 275 K - IN-SITU PHOTOLUMINESCENCE, EPR, AND FT-IR INVESTIGATIONS
ANPO, M
MATSUOKA, M
SHIOYA, Y
YAMASHITA, H
GIAMELLO, E
MORTERRA, C
CHE, M
PATTERSON, HH
WEBBER, S
OUELLETTE, S
FOX, MA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (22) : 5744 - 5750
[10] Anpo M, 2000, J IND ENG CHEM, V6, P59

← 1 2 3 4 5 6 7 8 9 10 →