An alternate route to the active chiral hydrogenation catalysts [Ru(bisphosphine)(H)(solvent)3]+:: Synthesis, characterization, and catalytic evaluation

被引：12

作者：

Wiles, JA ^{[1
]}

Daley, CJA ^{[1
]}

Hamilton, RJ ^{[1
]}

Leong, CG ^{[1
]}

Bergens, SH ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 20期

关键词：

D O I：

10.1021/om049740x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report an improved synthesis of cis-[Ru(CH3CN)(2)((1-3-eta)-C3H5)((1,2:5,6-eta)-C8H12)]BF4 and its use in the synthesis of [Ru(bisphosphine)((1-3:5,6-eta)-C8H11)(CH3CN)]BF4 (where bisphosphine = (R)-BINAP, (R)-Tol-BINAP). Thermolyses of the complexes [Ru(bisphosphine)((1-3:5,6-eta)-C8H11)(CH3CN)]BF4 afford [Ru(bisphosphine)((1-5-eta)-C8H11)]BF4, which serve as convenient precatalysts to the active hydrogenation catalysts fac-[Ru(bisphosphine)(H)(sol)(3)]BF4 (sol = THF, acetone, i-PrOH). We compare the properties and activities of these catalysts with those of related, established systems.

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页码：4564 / 4568

页数：5

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