Ketone coupling with alkyl iodides, bromides, and chlorides using thulium diiodide:: A more powerful version of SmI2(THF)x/HMPA

被引：70

作者：

Evans, WJ ^{[1
]}

Allen, NT ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 09期

关键词：

D O I：

10.1021/ja992951m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：2118 / 2119

页数：2

共 30 条

[1] Synthesis and structure of the first molecular thulium(II) complex: [TmI2(MeOCH(2)CH(2)OMe)(3)] [J].

Bochkarev, MN ;

Fedushkin, IL ;

Fagin, AA ;

Petrovskaya, TV ;

Ziller, JW ;

BroomhallDillard, RNR ;

Evans, WJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :133-135

[2] THE SAMARIUM GRIGNARD REACTION - INSITU FORMATION AND REACTIONS OF PRIMARY AND SECONDARY ALKYLSAMARIUM(III) REAGENTS [J].

CURRAN, DP ;

TOTLEBEN, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (15) :6050-6058

[3] Comparison of divalent dimethoxyethane-solvated thulium and samarium diiodides in hexamethylphosphoramide and pyridine:: Isolation of the cations {[TmI2(HMPA)4][I](pyridine)5} and {[TmI(HMPA)4(pyridine)][I]2} and a single crystal containing both linear and bent dimethoxyethane-solvated SmI2 [J].

Evans, WJ ;

Broomhall-Dillard, RNR ;

Ziller, JW .

POLYHEDRON, 1998, 17 (19) :3361-3370

[4] Samarium(II) triflate as a new reagent for the Grignard-type carbonyl addition reaction [J].

Fukuzawa, S ;

Mutoh, K ;

Tsuchimoto, T ;

Hiyama, T .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (16) :5400-5405

[5] DIVALENT LANTHANIDE DERIVATIVES IN ORGANIC-SYNTHESIS .1. MILD PREPARATION OF SMI2 AND YBI2 AND THEIR USE AS REDUCING OR COUPLING AGENTS [J].

GIRARD, P ;

NAMY, JL ;

KAGAN, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (08) :2693-2698

[6] ADDITIVE AND SOLVENT EFFECTS ON SMI2 REDUCTIONS - THE EFFECTS OF WATER AND DMPU [J].

HASEGAWA, E ;

CURRAN, DP .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (18) :5008-5010

[7] The Barbier reaction of 1-(chloromethyl)benzotriazole with aldehydes and ketones mediated by samarium diiodide [J].

Huang, ZZ ;

Jin, HW ;

Duan, DH ;

Huang, X .

JOURNAL OF CHEMICAL RESEARCH-S, 1999, (09) :564-565

[8] A MILD AND CONVENIENT METHOD FOR THE REDUCTION OF ORGANIC HALIDES BY USING A SMI2-THF SOLUTION IN THE PRESENCE OF HEXAMETHYLPHOSPHORIC TRIAMIDE (HMPA) [J].

INANAGA, J ;

ISHIKAWA, M ;

YAMAGUCHI, M .

CHEMISTRY LETTERS, 1987, (07) :1485-1486

[9] LANTHANIDES IN ORGANIC-SYNTHESIS [J].

KAGAN, HB ;

NAMY, JL .

TETRAHEDRON, 1986, 42 (24) :6573-6614

[10]

KAGAN HB, 1984, HDB PHYS CHEM RARE E, V6, pCH50

← 1 2 3 →