Pseudocapacitive properties of electrochemically prepared vanadium oxide on carbon nanotube film substrate

被引：58

作者：

Kim, Il-Hwan ^{[1
]}

Kim, Jae-Hong

Cho, Byung-Won

Kim, Kwang-Bum

机构：

[1] Yonsei Univ, Dept Met Engn, Seoul 120749, South Korea

[2] Res Ctr Energy Convers & Storage, Seoul 151744, South Korea

[3] Korea Inst Sci & Technol, Econano Res Ctr, Seoul 136701, South Korea

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2006年 / 153卷 / 08期

关键词：

D O I：

10.1149/1.2203936

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Vanadium oxide (V2O5 center dot xH(2)O) was electrodeposited on a carbon nanotube (CNT) film substrate with a three-dimensional porous structure at the nanometer scale as an electrode material for pseudocapacitors using organic electrolytes. Microstructures of the electrochemically prepared V2O5 center dot xH(2)O on the CNT film substrate (V2O5 center dot xH(2)O/CNT film electrode) showed that V2O5 center dot xH(2)O was heterogeneously nucleated and uniformly deposited on the CNT film substrate. The V2O5 center dot xH(2)O/CNT film electrode showed not only a high specific Li-ion capacitance of 1230 F/g with respect to the mass of the V2O5 center dot xH(2)O, but also a high rate capability. The maximum specific energy of 851 Wh/kg and specific power of 125 kW/kg were obtained from the discharging curves of the V2O5 center dot xH(2)O/CNT film electrode. They could be attributed to the electrode construction comprising a very thin film of V2O5 center dot xH(2)O deposited on the conductive CNT film substrate with a three-dimensional nanoporous structure. (c) 2006 The Electrochemical Society.

引用

页码：A1451 / A1458

页数：8

共 40 条

[1]

An KH, 2001, ADV MATER, V13, P497, DOI 10.1002/1521-4095(200104)13:7<497::AID-ADMA497>3.0.CO

[2]

2-H

[3] Lithium insertion into host materials: the key to success for Li ion batteries [J].

Broussely, M ;

Biensan, P ;

Simon, B .

ELECTROCHIMICA ACTA, 1999, 45 (1-2) :3-22

[4] Morphology control of thin LiCoO2 films fabricated using the electrostatic spray deposition (ESD) technique [J].

Chen, CH ;

Kelder, EM ;

vanderPut, PJJM ;

Schoonman, J .

JOURNAL OF MATERIALS CHEMISTRY, 1996, 6 (05) :765-771

[5] FABRICATION OF LICOO2 THIN-FILM CATHODES FOR RECHARGEABLE LITHIUM BATTERY BY ELECTROSTATIC SPRAY-PYROLYSIS [J].

CHEN, CH ;

BUYSMAN, AAJ ;

KELDER, EM ;

SCHOONMAN, J .

SOLID STATE IONICS, 1995, 80 (1-2) :1-4

[6]

Conway B. E., 1999, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, P33

[7]

Conway B. E., 1999, ELECTROCHEMICAL SUPE, P221, DOI DOI 10.1007/978-1-4757-3058-6_10

[8]

CONWAY BE, 1999, ELECTROCHEMICAL SUPE, P525

[9]

Dong W, 2000, ELECTROCHEM SOLID ST, V3, P457

[10] Electrochemical properties of vanadium oxide aerogels and aerogel nanocomposites [J].

Dong, W ;

Sakamoto, J ;

Dunn, B .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :641-644

← 1 2 3 4 →