Cholestane- and pregnane-type glycosides from the roots of Tribulus cistoides

被引：25

作者：

Achenbach, H ^{[1
]}

Hubner, H ^{[1
]}

Reiter, M ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST PHARMACOL & TOXICOL,W-8000 MUNICH,GERMANY

来源：

PHYTOCHEMISTRY | 1996年 / 41卷 / 03期

关键词：

Tribulus cistoides; Zygophyllaceae; roots; cardioactive saponin-3; cholestane-type glycosides; pregnane-type glycoside; D-(+)-pinitol; sucrose;

D O I：

10.1016/0031-9422(95)00622-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 [生物化学与分子生物学]; 081704 [应用化学];

摘要：

From the methanolic extract of the roots of Tribulus cistoides the cardioactive saponin-3, which is known to occur in the leaves, was isolated along with tribulosin, a pregnane-type glycoside and eight new cholestane glycosides. D-(+)-Pinitol and sucrose were major constituents. The structures were established by spectroscopic studies of the isolated compounds, their acetylated derivatives and their hydrolysation products. Chemical conversions revealed the configurations at C-22 and C-25, respectively.

引用

页码：907 / 917

页数：11

共 23 条

[1]

CARDIOACTIVE STEROID SAPONINS AND OTHER CONSTITUENTS FROM THE AERIAL PARTS OF TRIBULUS CISTOIDES [J].

ACHENBACH, H ;

HUBNER, H ;

BRANDT, WG ;

REITER, M .

PHYTOCHEMISTRY, 1994, 35 (06) :1527-1543

[2]

C-13 NMR SPECTRAL INVESTIGATIONS .10. C-13 NMR-SPECTROSCOPY OF STEROIDAL SAPOGENINS AND STEROIDAL SAPONINS [J].

AGRAWAL, PK ;

JAIN, DC ;

GUPTA, RK ;

THAKUR, RS .

PHYTOCHEMISTRY, 1985, 24 (11) :2479-2496

[3]

THE STRUCTURE OF PINITOL [J].

ANDERSON, AB ;

MACDONALD, DL ;

FISCHER, HOL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (06) :1479-1480

[4]

[Anonymous], INDICE SINONIMIA ZAS

[5]

AYENSU ES, 1981, MEDICINAL PLANTS W I

[6]

CHEMISTRY OF AYURVEDIC CRUDE DRUGS .5. GUGGULU (RESIN FROM COMMIPHORA-MUKUL) .5. SOME NEW STEROIDAL COMPONENTS AND, STEREOCHEMISTRY OF GUGGULSTEROL-I AT C-20 AND C-22 [J].

BAJAJ, AG ;

DEV, S .

TETRAHEDRON, 1982, 38 (19) :2949-2954

[7]

H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].

BAX, A ;

SUMMERS, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2093-2094

[8]

C-13 NMR-STUDIES .69. C-13 NMR-SPECTRA OF STEROIDS - SURVEY AND COMMENTARY [J].

BLUNT, JW ;

STOTHERS, JB .

ORGANIC MAGNETIC RESONANCE, 1977, 9 (08) :439-464

[9]

CONVENIENT SYNTHESIS OF (S)-(-)-PULEGONE FROM (-)-CITRONELLOL [J].

COREY, EJ ;

ENSLEY, HE ;

SUGGS, JW .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (02) :380-381

[10]

PROTECTION OF HYDROXYL GROUPS AS TERT-BUTYLDIMETHYLSILYL DERIVATIVES [J].

COREY, EJ ;

VENKATESWARLU, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (17) :6190-+

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