A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(II) - Part I. Preliminary studies

被引：191

作者：

Hazza, A ^{[1
]}

Pletcher, D ^{[1
]}

Wills, R ^{[1
]}

机构：

[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2004年 / 6卷 / 08期

关键词：

D O I：

10.1039/b401115e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This series of papers will describe the chemistry, electrochemistry and performance of a flow battery with no separator and a single electrolyte, lead(II) in methanesulfonic acid. Voltammetry at rotating disc electrodes is used to define the conditions for the high rate deposition and dissolution of lead and lead dioxide in aqueous methanesulfonic acid. The determination of lead methanesulfonate solubility and solution conductivity as a function of lead methanesulfonate and methanesulfonic acid concentrations was carried out in order to aid the selection of the electrolyte for the battery.

引用

页码：1773 / 1778

页数：6

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