Synthesis and characterization of a novel tetranuclear copper(II) resorc[4]arene complex possessing four structurally different copper centers

被引：25

作者：

Fox, OD ^{[1
]}

Dalley, NK ^{[1
]}

Harrison, RG ^{[1
]}

机构：

[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 03期

关键词：

D O I：

10.1021/ic990798r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new resorc[4]arene ligand with four bis(pyridyl-methylamine) coordinating moieties (bpa-res) is described. The tetranuclear copper(II) complex of bpa-res shows that the bpa-res ligand serves as a template to assemble four copper atoms in close proximity to each other. The complex possesses four structurally unique copper(II) ions in the solid state, two of which form a discrete binuclear complex within the tetranuclear complex.

引用

页码：620 / 622

页数：3

共 73 条

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