Single crystal X-ray structure of tetrahedral C60F36:: the most aromatic and distorted fullerene

被引：45

作者：

Hitchcock, PB ^{[1
]}

Taylor, R ^{[1
]}

机构：

[1] Univ Sussex, CPES Sch, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b205286p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tetrahedral C60F36 is shown by its single-crystal X-ray structure to be the most aromatic (and distorted) fullerene derivative, having four planar hexagons with almost equal bond lengths, the average of which (1.373 Angstrom) is the same as in C60F18; one exceptionally long FC-CF bond (1.665 Angstrom) corresponds to the similarly long bond in C60F18 (a motif of T C60F36) and is likely to be the site of oxygen insertion in C60F36O.

引用

页码：2078 / 2079

页数：2

共 12 条

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