Recent advances in asymmetric synthesis using chiral lithium amide bases

被引：61

作者：

Simpkins, NS

机构：

[1] Department of Chemistry, University of Nottingham, Nottingham NG7 2RD, University Park

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030691

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of chiral lithium amide bases for the asymmetric transformation of ketones and certain organometallics is described, including the effect of added salts on the enantiomeric excess achieved and an application involving the total synthesis of the alkaloid anatoxin-a.

引用

页码：691 / 694

页数：4

共 13 条

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[3] AN ENHANCEMENT OF ENANTIOSELECTIVITY IN CHIRAL LITHIUM AMIDE DEPROTONATIONS DUE TO LITHIUM-CHLORIDE [J].

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[5] THE EFFECT OF ADDED SALTS ON ENANTIOSELECTIVE TRANSFORMATIONS OF CYCLIC-KETONES BY CHIRAL LITHIUM AMIDE BASES [J].

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[10]

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