Tape casting of nanocrystalline ceria gadolinia powder

被引:54
作者
Meier, LP [1 ]
Urech, L [1 ]
Gauckler, LJ [1 ]
机构
[1] Swiss Fed Inst Technol, Lausanne, Switzerland
关键词
tape casting; CeO2; fuel cell; nanoparticles;
D O I
10.1016/j.jeurceramsoc.2004.01.002
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A ceramic ceria gadolinia solid solution membrane for solid oxide, fuel cells was fabricated by tape casting using a nanopowder of 37 nm average particle size. A novel combination of solvent and dispersant was used to disperse the nanoparticles. The polymer was added in a dilute stage to guarantee a homogeneous distribution. After casting a remarkable densification of the cast tape suspension from a solid loading of 20 up to 42 vol.% was observed during drying. The green tape was sintered to >92% theoretical density and was dense towards perfusion. The resulting grain size in the sintered specimen still was <200 nm. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3753 / 3758
页数:6
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