Heterogeneous shvo-type ruthenium catalyst: dehydrogenation of alcohols without hydrogen acceptors

被引：90

作者：

Choi, JH ^{[1
]}

Kim, N ^{[1
]}

Shin, YJ ^{[1
]}

Park, JH ^{[1
]}

Park, J ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, POSTECH, Ctr Integrated Mol Syst, Dept Chem,Div Mol & Life Sci, Pohang 790784, South Korea

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 24期

关键词：

silica sol-gel; diruthenium; dehydrogenation alcohols;

D O I：

10.1016/j.tetlet.2004.04.113

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Shvo-type diruthenium complex is heterogenized by a sol-gel process, which catalyzes the conversion of alcohols to carbonyl compounds and molecular hydrogen without any additive. The heterogeneous catalyst is recoverable by simple filtration, stable in the air, and reusable. (C) 2004 Elsevier Ltd. All rights reserved.

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收藏

页码：4607 / 4610

页数：4

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