Dimeric and monomeric forms of manganese N-confused porphyrin

被引：53

作者：

Harvey, JD ^{[1
]}

Ziegler, CJ ^{[1
]}

机构：

[1] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 17期

关键词：

D O I：

10.1039/b205345d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and structural characterization of a manganese adduct of N-confused tetraphenylporphyrin (NCTPP) is presented; in the absence of coordinating ligands this complex forms a novel dimer structure and demonstrates a potential manganese agostic interaction with the interior pyrrolic CH as seen in other first row transition metal NCTPP compounds.

引用

收藏

页码：1942 / 1943

页数：2

相关论文

共 14 条

[1]

Alder A. D., 1970, J INORG NUCL CHEM, V32, P2443

[2] Metal oxidation promoted C-H activation in manganese complexes of N-confused porphyrin [J].

Bohle, DS ;

Chen, WC ;

Hung, CH .

INORGANIC CHEMISTRY, 2002, 41 (13) :3334-3336

[3] SYNTHESIS AND CHARACTERIZATION OF NOVEL METAL(III) COMPLEXES OF CORROLE - CRYSTAL AND MOLECULAR-STRUCTURE OF (2,3,7,8,12,13,17,18-OCTAMETHYLCORROLATO)(TRIPHENYLARSINE)RHODIUM(III) [J].

BOSCHI, T ;

LICOCCIA, S ;

PAOLESSE, R ;

TAGLIATESTA, P ;

TEHRAN, MA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :463-468

[4]

Buchler J. W., 1978, PORPHYRINS, V1, P389

[5] Synthesis and characterization of iron N-confused porphyrins: Structural evidences of agostic interaction [J].

Chen, WC ;

Hung, CH .

INORGANIC CHEMISTRY, 2001, 40 (20) :5070-+

[6] Copper(II) complexes of inverted porphyrin and its methylated derivatives [J].

Chmielewski, PJ ;

Latos-Grazynski, L ;

Schmidt, I .

INORGANIC CHEMISTRY, 2000, 39 (24) :5475-5482

[7] ELECTROCHEMICAL REACTIVITY OF MANGANESE(II) PORPHYRINS - EFFECTS OF DIOXYGEN, BENZOIC ANHYDRIDE, AND AXIAL LIGANDS [J].

CREAGER, SE ;

MURRAY, RW .

INORGANIC CHEMISTRY, 1987, 26 (16) :2612-2618

[8] NH tautomerism of N-confused porphyrin [J].

Furuta, H ;

Ishizuka, T ;

Osuka, A ;

Dejima, H ;

Nakagawa, H ;

Ishikawa, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (25) :6207-6208

[9] N-CONFUSED PORPHYRIN - A NEW ISOMER OF TETRAPHENYLPORPHYRIN [J].

FURUTA, H ;

ASANO, T ;

OGAWA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (02) :767-768

[10] N-confused double-decker porphyrins [J].

Furuta, H ;

Kubo, N ;

Maeda, H ;

Ishizuka, T ;

Osuka, A ;

Nanami, H ;

Ogawa, T .

INORGANIC CHEMISTRY, 2000, 39 (24) :5424-5425