Crystal structure and magnetic properties of two-dimensional cyanide-bridged bimetallic assembly composed of CsI[MnII(3-cyanopyridine)2{WV(CN)8}]•H2O

被引：38

作者：

Arimoto, Y

Ohkoshi, S

Zhong, ZJ

Seino, H

Mizobe, Y

Hashimoto, K

机构：

[1] Univ Tokyo, Adv Sci & Technol Res Ctr, Meguro Ku, Tokyo 1538904, Japan

[2] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 08期

关键词：

D O I：

10.1246/cl.2002.832

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have synthesized a two-dimensional manganese(II) octacyanotungstate(V)-based ferrimagnet with a magnetic ordering temperature of 35 K. Single crystal analysis showed that Mn-II ion was axially capped by 3-cyanopyridines, forming a two-dimensional structure. This bimetallic assembly showed ferrimagnetic properties due to the antiferromagnetic interaction between magnetic orbitals of d(Z)2 on W-V ion and d(x'y') on Mn-II ion in the inside of the two dimensional layer.

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页码：832 / 833

页数：2

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