Double-bond isomerization of olefinic amines over potassium amide loaded on alumina

被引：12

作者：

Handa, H ^{[1
]}

Baba, T ^{[1
]}

Yamada, H ^{[1
]}

Takahashi, T ^{[1
]}

Ono, Y ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN

来源：

CATALYSIS LETTERS | 1997年 / 44卷 / 1-2期

关键词：

potassium amide; alumina; double-bond isomerization; olefinic amines;

D O I：

10.1023/A:1018952320020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Potassium amine loaded on alumina heated under vacuum at 573 K (KNH2/Al2O3) readily isomerizes N,N-diethyl-3,7-dimethyl-octa-2(Z),6-dienylamine to N,N-diethyl 3,7-dimethyl-octa-1(E),3-dienylamine, which was obtained in 99% yield at 313 K for 1 h with or without solvent. The double bond at the 1 position was 100% E. The ratio of E/Z of the double bond at the 3 position was almost 1/1.

引用

页码：119 / 121

页数：3

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