Shape-controlled synthesis and characterization of BaZrO3 microcrystals

被引：85

作者：

Lu, ZG

Tang, YG

Chen, LM

Li, YD ^{[1
]}

机构：

[1] Tsinghua Univ, Minist Educ China, Dept Chem, Key Lab Atom & Mol Nanosci, Beijing 100084, Peoples R China

[2] Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China

来源：

JOURNAL OF CRYSTAL GROWTH | 2004年 / 266卷 / 04期

基金：

中国国家自然科学基金;

关键词：

photoluminescence; shape control; hydro-thermal; barium zirconate; perovskites; rare earth compounds;

D O I：

10.1016/j.jcrysgro.2004.02.107

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A facile modified hydrothermal approach has been exploited to rationally synthesize perovskite-structured BaZrO3 microcrystals with the shapes of truncated rhombic dodecahedron and sphere. The polarity variation by ethanol introduction to the solutions plays a significant role in determining the geometric morphology of the final products. The BaZrO3 microcrystals can serve as host materials for rare earth photoluminescence, and shape-dependent luminescence properties of an Eu-doped material has been observed. Controlling the size and shape of perovskite oxides is of great importance both in basic and applied science due to their strong structure-dependent physical properties. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：539 / 544

页数：6

共 35 条

[1]

Alonso JA, 2000, ANGEW CHEM INT EDIT, V39, P619, DOI 10.1002/(SICI)1521-3773(20000204)39:3<619::AID-ANIE619>3.0.CO

[2]

2-O

[3] Epitaxial growth of Y-doped SrZrO3 films on MgO by pulsed laser deposition [J].