Structural and X-ray powder diffraction studies of nano-structured lead(II) coordination polymer with η2 Pb•••C interactions

被引：59

作者：

Ahmadzadi, Haida ^{[2
]}

Marandi, Farzin ^{[2
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

[2] Payame Noor Univ, Dept Chem, Abhar, Zanjan, Iran

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 22期

关键词：

Nano-structure; Coordination polymer; Lead(II); Pb center dot center dot center dot C interactions; LONE-PAIR; COMPLEXES; MERCURY(II); CRYSTAL; LIGAND; IRON;

D O I：

10.1016/j.jorganchem.2009.07.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new nano-sized Pb(II) one-dimensional coordination polymer with eta(2) Pb-C interactions, [Pb-2 (mu(3)-ba)(2)(mu(2)-ba)(2)](n) (1) [ba = benzylacetylacetonate] has been synthesized and characterized by SEM, X-ray powder diffraction, IR spectroscopy and elemental analyses. Single-crystal X-ray diffraction shows the coordination number of Pb(II) ions is seven and the lead atoms have hemidirected coordination sphere containing involving Pb center dot center dot center dot C interactions, C2O7Pb. PbO nanoparticles were obtained by calcinations of the nano-sized compound 1 at 600 degrees C. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：3565 / 3569

页数：5

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