Selective Aerobic Oxidation of Benzylic Alcohols Catalyzed by Carbon-Based Catalysts: A Nonmetallic Oxidation System

被引：98

作者：

Kuang, Yongbo ^{[1
]}

Islam, Nazrul M. ^{[1
]}

Nabae, Yuta ^{[1
]}

Hayakawa, Teruaki ^{[1
]}

Kakimoto, Masa-aki ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Organ & Polymer Mat, Meguro Ku, Tokyo 1528552, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 02期

关键词：

aerobic oxidation; alcohols; aldehydes; carbon; metal-free catalysis; OXYGEN REDUCTION ACTIVITY; NITRIC-ACID; METAL-FREE; NITROGEN; DEHYDROGENATION; CHEMISTRY;

D O I：

10.1002/anie.200904362

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Chemical Equation Presented" Swapping places: The use of carbon to replace transition metals in the selective aerobic oxidation of benzylic alcohols has been demonstrated to be feasible. The HNO3 additive is activated by the carbon catalyst NSC, which serves as the primary oxidant for alcohol oxidations and is regenerated by O2. NSC=nanoshell carbon. © 2010 Wiley-VCH Verlag GmbH &. Co. KGaA.

引用

页码：436 / 440

页数：5

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